Tobacco replacement material

ABSTRACT

A smoking material is disclosed which consists essentially of a vinyl methyl ether: maleic anhydride copolymer or salts thereof, an inorganic particulate filler and optionally a second combustible material. The second combustible filler may be of tobacco dust, sodium gluconate, pectins, natural gums, or cellulose or its derivative. Inorganic particulate material serves in the capacity of a combustion modifier and reduces the total effective combustible material in a particular charge.

States Patent 1191 [111 3,842,845 Cartwright 1 Oct. 22, 1974 [54] TOBACCO REPLACEMENT MATERIAL 3,145,717 8/1964 Osborne et al 131/140 C 3,407,15 10/1968 Cartensen et a1. 260/785 T [751 lnvemorwllllam Franc Cammgh" 3,461,879 8/1969 Kirkland et a1. 131/2 Charlotte, 3,529,602 8/1969 Hind et al. 131/2 [73] Assigneez Celanese Corporation New York, 3,545,448 12/1970 Mormon et al. 131 2 [22] Filed: Oct. 25, 1973 Primary Examiner-Melvin D. Rem

[21] Appl. No.: 409,568

Related U.S. Application Data [57] ABSTRACT [62] Division of Ser. No. 224,997, Feb. 9, 1972, Pat. No. A smoking material is disclosed which consists essen- 3,812,864. tially of a vinyl methyl ether: maleic anhydride copolymer or salts thereof, an inorganic particulate filler and [52] U.S. Cl. 131/2, 131/17 R optionally a second combustible material. The second [51 Int. Cl A24b 15/00 combustible filler may be of tobacco dust, sodium glu- [58] Field of Search 131/2, 140-144, conate, pectins, natural gums, or cellulose or its deriv- 131/17 ative. Inorganic particulate material serves in the capacity of a combustion modifier and reduces the total [56] References Cited effective combustible material in a particular charge.

UNITED STATES PATENTS 3 Cl N D 2,866,775 12 1958 Sellers 260/785 T o rawmgs TOBACCO REPLACEMENT MATERIAL This is a division, of application Ser. No. 224,997, filed Feb. 9, 1972, now US. Pat. No. 3,812,864.

The present invention relates generally to products which may be smoked in cigarettes, cigars, pipes, etc., either alone or in combination with tabacco, reconstituted tabacco or other smoking materials, and more specifically, relates to new types of tabacco substitutes.

It is believed by many practitioners in the relevant art that the smoking of tabacco, while a widespread practice, may tend to have adverse effects on the smokers health if the practice is continued over a significant time period. These effects are believed to be attributable to the presence in tobacco smoke of various undesirable pyrolysis components. Furthermore, such components tend to irritate the smokers respiratory passages, particularly in the nose and throat. From a production standpoint, tabacco is also undesirable because of variations in availability and uniformity from season to season.

As a result of the above factors, prior art workers have attempted to develop tabacco substitutes which would deliver reduced amounts of undesirable pyrolysis components and be independent of a growing season while still being aesthetically acceptable to the smoker.

As examples of such attempts, U.S. Pat. No. 3,461,879, issued Aug. 19, 1969, describes tobacco substitutes in which the combustible portion is oxidized cellulose or contains a significant percentage of alpha cellulose; US. Pat. No. 3,529,602, issued Sept. 22, 1970, describes tobacco substitutes in which tobacco pectins are employed as a combustible binder; and Canadian Pat. No. 822,969, issued Sept. 16, 1969, describes tobacco substitutes comprised of thermally degraded cellulose. Particularly desirable tobacco substitutes are disclosed in British Pat. No. 1,244,441, published Sept. 2, 1971. The tobacco substitutes described in this latter patent comprise as a combustible binder, various starch or cellulose ethers.

While the foregoing substitutes have been sucessful to varying degrees in overcoming the disadvantages of tobacco, there still exists a need for an improved tobacco substitute. Accordingly, it is the primary object of the present invention to provide a tobacco substitute overcoming the aforesaid disadvantages of tobacco. Within this primary objective, it is also an object of the present invention to provide a process for preparing these tobacco substitutes.

Tobacco substitutes are comprised generally of a combustible substance in combination with one or more materials which alter the burning rate of the combustible substance to simulate that of tobacco. The combustible substances employed in tobacco substitutes have been either naturally occurring polymers, e.g., cellulose, starch or vegetable gums; or derivatives of such materials, e.g., thermally degraded cellulose, oxidized cellulose, or starch and cellulose ethers. To the contrary, the combustible substances used in the present invention are totally synthetic polymers.

More specifically, the present invention contemplates tobacco substitutes in which the combustible substance is a compolymer of vinyl methyl ether and maleic anhydride. These copolymers are comprised on the repeating unit oon3 -ca, b

Miami 1 is] may also be used in the present inventions. Preferred are the polymers which in their anhydrous state would have a specific viscosity corresponding to that noted above.

Salts, particularly the alkali and alkaline earth metal salts, of the foregoing copolymers in both the anhydrous and hydrolyzed forms may also be used, as may mixtures of the foregoing polymers.

For the sake of brevity the foregoing polymers, including the hydrolyzed polymers and salts will be referred to by the designation PVM/MA." Unless otherwise specified, any reference to percent or percentage is intended to mean percent by weight of the tobacco substitute.

In preparing the present tobacco substitutes, from about 15 to about 85, and preferably from about 20 to about 50 percent PVM/MA is intimately mixed in either a dry state or dissolved in water with from about 15 to about 85, and preferably about 50 to about percent of a conventional combustion modifier. This mixture, normally in a 65 to aqueous solution is then cast into a film, preferably having a dried thickness of from about 3 to about 15 mils.

The combustion modifiers employed in the present compositions, which may also serve to varying degrees as fillers which reduce the total amount of combustible substance present, and thus the total amount of com-' bustion products, are non-toxic particulate materials, preferably having an average minimum dimension of from about 0.2 microns to about 1.0 millimeter. Even more preferably, the particles will have an average minimum dimension of from about 0.05 millimeter. It is also preferred that the particulate materials have a maximum dimension of about 0.25 mm, and more preferably, about 0.10 mm. Suitable materials can be selected from organic compounds, inorganic compounds and the elements, so long as the material selected is non-toxic, i.e., pharmacologically inactive in the sense of significant adverse effects in a causative relationship upon oral ingestion of the substance itself or its combustion products. However, a reduced delivery of undesirable components is more readily observed when the particulate material comprises an inorganic compound, an element or a mixture thereof.

Inorganic compounds which may be used as fillers may be comprised of a cation selected from Column (A) and an anion selected from Column (B).

Preferably, the cations employed will be selected from the group consisting of zinc, titanium, magnesium, calcium, aluminum, and iron. Desirably, these cations are in the form of the carbonates, oxides, hydroxides, sulfates, phosphates, aluminates, silicates and alumino silicates. The oxides, carbonates and hydroxides are particularly desirable since these anions decompose to carbsn, hydrogen and oxygen upon combustion. Inorganic compounds in their natural occurring states, such as limestone, diatomaceous earth, perlite, magnesite, vermiculite, etc. are also suitable.

As previously noted, elements may also be used as filler materials. Preferred elements include carbon, zinc, magnesium, titanium, aluminum, and iron.

While the filler materials are generally granular in nature, they may also be in fibrous form. Materials readily useable in fibrous from are fiberglass, mica, asbestos, metal, metal oxide, and metal carbide whiskers. For the purposes of the present invention, thin metal strips such as aluminum shaving are considered to be fibrous. Preferably the fibrous materials will have an average length of from about 0.1 mm to about 5 mm., and an average minimum dimension of the magnitude previously noted.

It is also within the scope of the present invention to employ combinations of particulate fillers in order to obtain the ultimate smouldering rate desired. Fillers found to be particularly suitable in controlling smouldering rates include titanium dioxide, carbon, magnesium oxide, zeolite silica gel, magnesium silicate, and diatomaceous earth.

If desired, the present tobacco substitutes may include a minor amount of a secondary combustible substance uniformly incorporated therein. Such materials include tobacco dust; sodium gluconate; pectins; natural gums, e.g., guar gum; cellulose, cellulose ethers and esters, and oxidized cellulose. To preserve film integrity and maintain filling power of the film, this optional second combustible material may be used in an amount of from zero to 40 percent of the total product with up to 30% being preferred.

Combinations of the present materials within the specified percentages will generally produce a smoking material yielding an ash comparable to that of tobacco. If desired, however, the type of ash formation and appearance thereof can be readily modified by the addition of various substances as fiberglass, potassium salts,

organic fibers, or phosphates, and non-toxic hydrated metal salts generally.

The materials of the preceding nature produce a smoke which in itself is relatively odorless and tasteless. This property permits a wide range of modification of taste and odor by incorporating into the material a variety of flavorants. Exemplary materials which have been found to be desirable in modifying the taste and ordor properties of the present smoking material include tobacco extracts, fruit extracts, synthetic flavorants, natural gums, resins, and sugars. Nicotine and other alkaloids, while not essential ingredients in the present compositions, may also be added in controlled amounts.

In the preparation of cigaretts, the foregoing films are normally shredded to a width of about 16-60 cuts per inch and wrapped in paper. The amount of combustion modifier used should be the amount necessary to produce a puff count of 5-12 when a cigarette of conventional dimensions, i.e., 8 mm in diameter and mm in length is smoked to a 30 mm butt length on an apparatus taking 35 ml. puffs over 2-second interval on a 60- second cycle.

As previously indicated, smoking products may be prepared using the present tobacco substitutes alone or in combination with tobacco, reconstituted tobacco or other tobacco substitutes. Desirably, however, the present tobacco substitutes should constitute at least 5 percent and preferably at least 10 percent of the blend.

The following examples are presented as illustrative of the present invention and should not be construed as in limitation thereof.

EXAMPLE I Ingredient Amt.(Grams) Gantrez AN-lo) Pectin Dolomite Diatomaccous Earth Carbon Glycerine Coloring Agents 99 9 5. cuccoc Pectin was dissolved in ml. of water. The remaining ingredients were added and the mixture stirred for 10 minutes. A film cast from the mixture, while somewhat brittle, burned with limited smoke and very little odor.

EXAMPLE II Ingredient Amt.(Grams) Gantrez HY-H l Hydrated Alumina l Diatomaceous Earth 1 Carbon Glycerine Coloring Agents EXAM PLE lll Ingredient Amtlflmms) Gantrez HY-L 10.0 Hydroxycthyl Cellulose 2.0 Carbon 0.4 Glycerine 4.0 Coloring Agents 0.18 Dolomite I21) Diatomaceous Earth 10.0 KCIOH 2.0

A film was prepared by mixing of the above ingredients in water, followed by casting of a film and drying at 125C for about 6 minutes. A piece of this film burned with a good ash, a good smouldering appearance and a rather mild sidestream. The sheet also exhibited excellent water resistance.

The above ingredients were mixed into 100 ml. of water and a film was cast from the mixture. The film, while initially relatively brittle, acquired flexibility upon steaming. lt burned well with a bland odor, and

good ash and smouldering properties.

EXAMPLE V Ingredient Amt.(Grams) (iuntrcz HY-H Gantrez HY-L Hydroxyethyl Cellulose Limestone Diutomaccous Earth Glyccrinc Carbon Coloring Agents A film cast from the foregoing ingredients was also observed to have good smouldering rate and a bland odor.

EXAMPLE Vl lllgl'ctlicnl Amt.((lrums) Gantrez HY-L 9.0 Hydroxyethyl Cellulose 3.0 Limestone 10.0 Diatomaceous Earth 15.0 Reten A-l* 4.0 Carbon 0.4 Coloring Agents 0.18

"Rcten A-l is a trademark of Hercules. Inc. for a proprietary cross-linking agent.

A film cast from the above ingredients was also observed to have good ashing properties and smouldering irate. Smoking in cigarettes form yielded a bland sidestream odor and a mild mainstream taste.

While the present invention has been described with specific illustrations, it is to be understood that many modifications may be made thereto without departing from the spirit and scope thereof.

What is claimed is:

l. A process for preparing an improved tobacco substitute comprising mixing 1. 15-85 percent by weight of a combustible material selected from the group consisting of vinyl methyl ether: maleic anhydride copolymer and the hydrolyzed or salt forms thereof;

2. 15-85 percent by weight of a particulate inorganic material selected from the group consisting of limestone; dolomite diatomaceous earth; perlite; magnesite; vermiculite; and salts having a cation selected from the group consisting of zinc, titanium, magnesium, calcium, aluminum and iron and an anion selected from the group consisting of the carbonate, oxides, hydroxides, sulphates, phosphates, aluminates, silicates and alumino-silicates; and

3. 0-40 percent by weight of a secondary combustible material selected from the group consisting of tobacco dust, sodium gluconates, pectin, natural gums, cellulose, cellulose ethers and esters, and oxidized cellulose; casting a film of the mixture in aqueous state, and drying said film.

2. The process of claim 1, wherein said mixture contains from about 65 to about percent water at the time of casting.

3. The process of claim 1, wherein said film is cast to a dried thickness of from about 3 to about 15 mils. 

1. A PROCESS FOR PREPARING AN IMPROVED TOBACCO SUBSTITUTE COMPRISING MIXING
 1. 15-85 PERCENT BY WEIGHT OF A COMBUSTIBLE MATERIAL SELECTED FROM THE GROUP CONSISTING OF VINYL METHYL ETHER: MALEIC ANHYDRIDE COPOLYMER AND THE HYDROLYZED OR SALT FORMS THEREOF.
 2. 15-85 PERCENT BY WEIGHT OF A PARTICULATE INORGANIC MATERIAL SELECTED FROM THE GROUP CONSISTING OF LIMESTONE; DOLOMITE DIATOMACEOUS EARTH; PERLITE; MAGNESITE; VERMICULITE; AND SALTS HAVING A CATION SELECTED FROM TJE GROUP CONSISTING OF ING OF ZINC, TITANIUM, MAGNESIUM, CALCIUM, ALUMINUM AND IRON AND AN ANION SELECTED FROM THE GROUP CONSISTING OF THE CARBONATE, OXIDES, HYDROXIDES, SULPHATES, PHOSPHATES, ALUMINATES, SILICATES AND ALUMINO-SILICATES; AND
 3. 0-40 PERCENT BY WEIGHT OF A SECONDARY COMBUSTIBLE MATERIAL SELECTED FROM THE GROUP CONSISTING OF TOBACCO DUST, SODIUM GLUCONATES, PECTIN, NATURAL GUMS, CELLULOSE, CELLULOSE ETHERS AND ESTERS, AND OXIDIZED CELLULOSE; CASTING A FILM OF THE MIXTURE IN AQUEOUS STATE, AND DRYING SAID FILM.
 2. 15-85 percent by weight of a particulate iNorganic material selected from the group consisting of limestone; dolomite diatomaceous earth; perlite; magnesite; vermiculite; and salts having a cation selected from the group consisting of zinc, titanium, magnesium, calcium, aluminum and iron and an anion selected from the group consisting of the carbonate, oxides, hydroxides, sulphates, phosphates, aluminates, silicates and alumino-silicates; and
 2. The process of claim 1, wherein said mixture contains from about 65 to about 95 percent water at the time of casting.
 3. The process of claim 1, wherein said film is cast to a dried thickness of from about 3 to about 15 mils.
 3. 0-40 percent by weight of a secondary combustible material selected from the group consisting of tobacco dust, sodium gluconates, pectin, natural gums, cellulose, cellulose ethers and esters, and oxidized cellulose; casting a film of the mixture in aqueous state, and drying said film. 